Tubular graphite cones.
نویسندگان
چکیده
We report the synthesis of tubular graphite cones using a chemical vapor deposition method. The cones have nanometer-sized tips, micrometer-sized roots, and hollow interiors with a diameter ranging from about 2 to several tens of nanometers. The cones are composed of cylindrical graphite sheets; a continuous shortening of the graphite layers from the interior to the exterior makes them cone-shaped. All of the tubular graphite cones have a faceted morphology. The constituent graphite sheets have identical chiralities of a zigzag type across the entire diameter, imparting structural control to tubular-based carbon structures. The tubular graphite cones have potential for use as tips for scanning probe microscopy, but with greater rigidity and easier mounting than currently used carbon nanotubes.
منابع مشابه
Directly observable G band splitting in Raman spectra from individual tubular graphite cones
Individual tubular graphite cones (TGCs) are characterized using Raman spectroscopy at room temperature. A split G band at 1569 − 1587 cm is directly observed from the root to the tip of TGCs without requiring surface electromagnetic and chemical enhancement effects. The G band can be deconvoluted into two Lorentzian peaks at 1571 ± 2 and 1584 ± 3 cm, which may be attributed to the resonance en...
متن کاملMicro- and Nano-scale Graphite Cones and Tubes from Hackman Valley, Kola Peninsula, Russia
Several unusual forms of natural graphite from an alkaline pegmatite that crosscuts rischorrite in the Hackman Valley, Khibiny Massif, Kola Peninsula, Russia are described. The graphite occurs macroscopically in two forms: as spherical aggregates up to 2 cm in diameter of friable, radially-aligned fibers ~20 μm in cross section, and as finegrained surface coatings in cavities covering aegirine,...
متن کاملGRAPHITE, TUBULAR PAHs, AND THE DIFFUSE INTERSTELLAR BANDS
Planar polycyclic aromatic hydrocarbons (PAHs) are candidates for the diffuse interstellar band (DIB) carriers. Nanometer-size Fe metallic particles, expected to be present during astrophysical graphite growth, are catalytic for formation of a related species—large tubular PAH molecules. We propose that tubular PAH molecules are a component of the interstellar medium. Electronic structure calcu...
متن کاملCarbon nanocones: wall structure and morphology.
Large-scale production of conical carbon nanostructures is possible through pyrolysis of hydrocarbons in a plasma torch process. The resulting carbon cones occur in five distinctly different forms, and disc-shaped particles are produced as well. The structure and properties of these carbon cones and discs have been relatively little explored until now. Here we characterize the structure of thes...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید
ثبت ناماگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید
ورودعنوان ژورنال:
- Science
دوره 300 5618 شماره
صفحات -
تاریخ انتشار 2003